feat: Expose equation exports (#869)

* pin new docling-core and exploit it via assembler changes

Signed-off-by: Michele Dolfi <dol@zurich.ibm.com>

* update test results

Signed-off-by: Michele Dolfi <dol@zurich.ibm.com>

* update with docling-core release

Signed-off-by: Michele Dolfi <dol@zurich.ibm.com>

---------

Signed-off-by: Michele Dolfi <dol@zurich.ibm.com>
This commit is contained in:
Michele Dolfi
2025-02-03 10:31:19 +01:00
committed by GitHub
parent 0cd81a8122
commit 6a76b49a47
19 changed files with 138 additions and 122 deletions

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@@ -112,25 +112,25 @@ Examples of the first fluorescent material 71 specifically include fluorescent m
(ij)MgO.(j/2)Sc₂O₃.kMgF₂.mCaF₂.(1n)GeO₂.(n/2)Mt₂O₃:zMn⁴⁺ (I)
wherein Mt is at least one selected from the group consisting of Al, Ga, and In, and j, k, m, n, and z are numbers satisfying 2≦i≦4, 0≦j<0.5, 0<k<1.5, 0≦m<1.5, 0<n<0.5, and 0<z<0.05, respectively.
wherein Mt is at least one selected from the group consisting of Al, Ga, and In, and j, k, m, n, and z are numbers satisfying 2≦i≦4, 0≦j&lt;0.5, 0&lt;k&lt;1.5, 0≦m&lt;1.5, 0&lt;n&lt;0.5, and 0&lt;z&lt;0.05, respectively.
(Ca₁₋p₋qSrpEuq)AlSiN₃ (II)
wherein p and q are numbers satisfying 0≦p≦1.0, 0<q<1.0, and p+q<1.0.
wherein p and q are numbers satisfying 0≦p≦1.0, 0&lt;q&lt;1.0, and p+q&lt;1.0.
MªvMbwMcfAl₃₋gSigNh (III)
wherein Mª is at least one element selected from the group consisting of Ca, Sr, Ba, and Mg, Mb is at least one element selected from the group consisting of Li, Na, and K, Mc is at least one element selected from the group consisting of Eu, Ce, Tb, and Mn, v, w, f, g, and h are numbers satisfying 0.80≦v≦1.05, 0.80≦w≦1.05, 0.001<f≦0.1, 0≦g≦0.5, and 3.0≦h≦5.0, respectively.
wherein Mª is at least one element selected from the group consisting of Ca, Sr, Ba, and Mg, Mb is at least one element selected from the group consisting of Li, Na, and K, Mc is at least one element selected from the group consisting of Eu, Ce, Tb, and Mn, v, w, f, g, and h are numbers satisfying 0.80≦v≦1.05, 0.80≦w≦1.05, 0.001&lt;f≦0.1, 0≦g≦0.5, and 3.0≦h≦5.0, respectively.
(Ca₁₋r₋s₋tSrrBasEut)₂Si₅N₈ (IV)
wherein r, s, and t are numbers satisfying 0≦r≦1.0, 0≦s≦1.0, 0<t<1.0, and r+s+t≦1.0.
wherein r, s, and t are numbers satisfying 0≦r≦1.0, 0≦s≦1.0, 0&lt;t&lt;1.0, and r+s+t≦1.0.
(Ca,Sr)S:Eu (V)
A₂[M¹₁₋uMn⁴⁺uF₆] (VI)
wherein A is at least one selected from the group consisting of K, Li, Na, Rb, Cs, and NH₄⁺, M¹ is at least one element selected from the group consisting of Group 4 elements and Group 14 elements, and u is the number satisfying 0<u<0.2.
wherein A is at least one selected from the group consisting of K, Li, Na, Rb, Cs, and NH₄⁺, M¹ is at least one element selected from the group consisting of Group 4 elements and Group 14 elements, and u is the number satisfying 0&lt;u&lt;0.2.
The content of the first fluorescent material 71 in the fluorescent member 50 is not particularly limited as long as the R/B ratio is within a range of 2.0 or more and 4.0 or less. The content of the first fluorescent material 71 in the fluorescent member 50 is, for example, 1 part by mass or more, preferably 5 parts by mass or more, and more preferably 8 parts by mass or more, per 100 parts by mass of the sealing material, and is preferably 200 parts by mass or less, more preferably 150 parts by mass or less, and still more preferably 100 parts by mass or less, per 100 parts by mass of the sealing material. When the content of the first fluorescent material 71 in the fluorescent member 50 is within the aforementioned range, the light emitted from the light emitting element 10 can be efficiently subjected to wavelength conversion, and light capable of promoting growth of plant can be emitted from the light emitting device 100.
@@ -148,7 +148,7 @@ The second fluorescent material 72 is preferably a fluorescent material having t
(Ln₁₋ₓ₋yCeₓCry)₃M₅O₁₂ (1)
wherein Ln is at least one rare earth element selected from the group consisting of rare earth elements excluding Ce, M is at least one element selected from the group consisting of Al, Ga, and In, and x and y are numbers satisfying 0.0002<x<0.50 and 0.0001<y<0.05, respectively.
wherein Ln is at least one rare earth element selected from the group consisting of rare earth elements excluding Ce, M is at least one element selected from the group consisting of Al, Ga, and In, and x and y are numbers satisfying 0.0002&lt;x&lt;0.50 and 0.0001&lt;y&lt;0.05, respectively.
In this case, the second fluorescent material 72 has a composition constituting a garnet structure, and therefore is tough against heat, light, and water, has an absorption peak wavelength of excited absorption spectrum in the vicinity of 420 nm or more and 470 nm or less, and sufficiently absorbs the light from the light emitting element 10, thereby enhancing light emitting intensity of the second fluorescent material 72, which is preferred. Furthermore, the second fluorescent material 72 is excited by light having light emission peak wavelength in a range of 380 nm or more and 490 nm or less and emits light having at least one light emission peak wavelength in a range of 680 nm or more and 800 nm or less.
@@ -156,9 +156,9 @@ In the second fluorescent material 72, from the standpoint of stability of a cry
In the second fluorescent material 72, the value of the parameter x is more preferably in a range of 0.0005 or more and 0.400 or less (0.0005≦x≦0.400), and still more preferably in a range of 0.001 or more and 0.350 or less (0.001≦x≦0.350).
In the second fluorescent material 72, the value of the parameter y is preferably in a range of exceeding 0.0005 and less than 0.040 (0.0005<y<0.040), and more preferably in a range of 0.001 or more and 0.026 or less (0.001≦y≦0.026).
In the second fluorescent material 72, the value of the parameter y is preferably in a range of exceeding 0.0005 and less than 0.040 (0.0005&lt;y&lt;0.040), and more preferably in a range of 0.001 or more and 0.026 or less (0.001≦y≦0.026).
The parameter x is an activation amount of Ce and the value of the parameter x is in a range of exceeding 0.0002 and less than 0.50 (0.0002<x<0.50), and the parameter y is an activation amount of Cr. When the value of the parameter y is in a range of exceeding 0.0001 and less than 0.05 (0.0001<y<0.05), the activation amount of Ce and the activation amount of Cr that are light emission centers contained in the crystal structure of the fluorescent material are within optimum ranges, the decrease of light emission intensity due to the decrease of light emission center can be suppressed, the decrease of light emission intensity due to concentration quenching caused by the increase of the activation amount can be suppressed, and light emission intensity can be enhanced.
The parameter x is an activation amount of Ce and the value of the parameter x is in a range of exceeding 0.0002 and less than 0.50 (0.0002&lt;x&lt;0.50), and the parameter y is an activation amount of Cr. When the value of the parameter y is in a range of exceeding 0.0001 and less than 0.05 (0.0001&lt;y&lt;0.05), the activation amount of Ce and the activation amount of Cr that are light emission centers contained in the crystal structure of the fluorescent material are within optimum ranges, the decrease of light emission intensity due to the decrease of light emission center can be suppressed, the decrease of light emission intensity due to concentration quenching caused by the increase of the activation amount can be suppressed, and light emission intensity can be enhanced.
### Production Method of Second Fluorescent Material
@@ -218,7 +218,7 @@ wherein M¹¹ is at least one selected from the group consisting of Ca, Sr, Ba,
Si₆₋bAlbObN₈₋b:Eu (ii)
wherein b satisfies 0<b<4.2.
wherein b satisfies 0&lt;b&lt;4.2.
M¹³Ga₂S₄:Eu (iii)
@@ -365,7 +365,7 @@ The above disclosed subject matter shall be considered illustrative, and not res
4. The light emitting device according to claim 2, wherein the another fluorescent material contains a first element Ln containing at least one element selected from the group consisting of rare earth elements excluding Ce, a second element M containing at least one element selected from the group consisting of Al, Ga and In, Ce, and Cr, and has a composition of an aluminate fluorescent material, and when a molar ratio of the second element M is taken as 5, a molar ratio of Ce is a product of a value of a parameter x and 3, and a molar ratio of Cr is a product of a value of a parameter y and 3, the value of the parameter x being in a range of exceeding 0.0002 and less than 0.50, and the value of the parameter y being in a range of exceeding 0.0001 and less than 0.05.
5. The light emitting device according to claim 2, wherein the another fluorescent material has the composition represented by the following formula (I): (Ln₁₋ₓ₋yCeₓCry)₃M₅O₁₂ (I) wherein Ln is at least one rare earth element selected from the group consisting of rare earth elements excluding Ce, M is at least one element selected from the group consisting of Al, Ga, and In, and x and y are numbers satisfying 0.0002<x<0.50 and 0.0001<y<0.05.
5. The light emitting device according to claim 2, wherein the another fluorescent material has the composition represented by the following formula (I): (Ln₁₋ₓ₋yCeₓCry)₃M₅O₁₂ (I) wherein Ln is at least one rare earth element selected from the group consisting of rare earth elements excluding Ce, M is at least one element selected from the group consisting of Al, Ga, and In, and x and y are numbers satisfying 0.0002&lt;x&lt;0.50 and 0.0001&lt;y&lt;0.05.
6. The light emitting device according to claim 2, the light emitting device being used in plant cultivation.